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Mild and in situ photo-crosslinking of anthracene-functionalized poly (aryl ether ketone) for enhancing temporal stability of organic NLO materials
- Source :
- Journal of Materials Science. 56:5910-5923
- Publication Year :
- 2021
- Publisher :
- Springer Science and Business Media LLC, 2021.
-
Abstract
- Developing a mild and efficient method to simultaneously enhance poling efficiency and temporal stability is meaningful and challenging for organic second-order nonlinear optical materials. In this paper, a new poly (aryl ether ketone) and chromophores functionalized with anthracene groups have been designed and prepared. Poling and crosslinking process could be separated by the mild and photo-initiated cycloaddition of anthracene group. As the UV–Vis spectrum, DSC and TGA curves, the networks had formed by 30-min irradiation of the Lower-power UV light which led little decomposition of dipolar chromophores. The maximum electro-optic coefficient (r33) of these polymers is 28.5 pm V−1 (at 1.3 μm), and the order parameter reaches 0.22. Moreover, the depolarization temperature of α peak, related to the dipole relaxation, has been increased to 129 °C after crosslinking, which is 17 °C higher than uncrosslinked ones. All these results indicated that the photo-crosslinking of anthracene exhibited promising potential for improving alignment stability and NLO activity at the same time.
- Subjects :
- chemistry.chemical_classification
Anthracene
Materials science
Ketone
020502 materials
Mechanical Engineering
Aryl
Poling
Ether
02 engineering and technology
Polymer
Chromophore
Photochemistry
Cycloaddition
chemistry.chemical_compound
0205 materials engineering
chemistry
Mechanics of Materials
General Materials Science
Subjects
Details
- ISSN :
- 15734803 and 00222461
- Volume :
- 56
- Database :
- OpenAIRE
- Journal :
- Journal of Materials Science
- Accession number :
- edsair.doi...........87541184a23eaeb11323b112ac43f94f