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Crystal and electronic structures and physical properties of Tc=10.4 K superconductor, (BEDT-TTF)2Cu(NCS)2

Authors :
Shoichi Sato
Tadashi Sugano
Tamotsu Inabe
Kokichi Oshima
Yusei Maruyama
Hatsumi Urayama
Hideki Yamochi
Atsushi Kawamoto
G. Saito
Jiro Tanaka
Takehiko Mori
M. Kinoshita
Hiroo Inokuchi
Source :
Synthetic Metals. 27:A393-A400
Publication Year :
1988
Publisher :
Elsevier BV, 1988.

Abstract

(BEDT-TTF)2Cu(NCS)2 was found to be the first ambient pressure organic superconductor with the Tc higher than 10 K. The salt has a layered structure which is composed of donor and anion sheets. The packing pattern of donors of the Cu(NCS)2 salt is nearly analogous to κ-(BEDT-TTF)2I3. In anion layers CuI is trigonal coordinated to two N atoms and one S atom to construct a one-dimensional planar polymer. The valence state of CuI was observed by ESCA at 298 K and ESR at 298-4 K. One broad Lorentzian ESR signal ascribed to a BEDT-TTF cation radical was obtained. The g-values are independent of temperature, while the linewidth shows broadening with lowering temperature even though the resistivity decreases below 90 K. The ESR magnetic susceptibility is constant down to 90 K, which is suggesting Pauli-like paramagnetism. The thermopower is anisotropic in the two-dimensional bc plane, which is originated from the anisotropy of the band structure.

Details

ISSN :
03796779
Volume :
27
Database :
OpenAIRE
Journal :
Synthetic Metals
Accession number :
edsair.doi...........880a1a8a1e79ba92bea46e6d1df0e674
Full Text :
https://doi.org/10.1016/0379-6779(88)90429-8