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Review – recent development of ring-opening polymerization of cyclic esters using aluminum complexes
- Source :
- Designed Monomers and Polymers. 17:345-355
- Publication Year :
- 2013
- Publisher :
- Informa UK Limited, 2013.
-
Abstract
- With the development of the technology of ring-opening polymerization (ROP) rapidly, many novel aluminum complexes have been designed, synthesized, and applied in initiating ROP of cyclic esters and new stereoregular polymerization mechanism of lactide polymerization have been reported. In this review, the mechanism for ROP of cyclic ester, synthesis of aluminum complexes containing tetradendete ligand, tridentate ligand, bidentate ligand, and bimetallic complexes containing aluminum were reviewed. We hope to give some helpful information for designing aluminum complexes, improving activity, and stereoregularity of aluminum complexes.
- Subjects :
- inorganic chemicals
Tridentate ligand
Lactide
Materials science
Polymers and Plastics
Ligand
General Chemical Engineering
chemistry.chemical_element
General Chemistry
complex mixtures
Ring-opening polymerization
eye diseases
chemistry.chemical_compound
chemistry
Polymerization
Aluminium
Polymer chemistry
Materials Chemistry
Ionic polymerization
Bimetallic strip
Subjects
Details
- ISSN :
- 15685551
- Volume :
- 17
- Database :
- OpenAIRE
- Journal :
- Designed Monomers and Polymers
- Accession number :
- edsair.doi...........8964c59bfc9086c46aba4054351c7c20