High exo:endo rate ratios in the solvolysis of the 2-methyl- and 2-phenyl-exo-5,6-trimethylene-2-norbornyl p-nitrobenzoates. Evidence for the unimportance of .sigma. participation in the high exo:endo rate ratios in tertiary norbornyl derivatives

Subjects

Subjects :

Colloid and Surface Chemistry
Stereochemistry
Chemistry
Nitrobenzoates
General Chemistry
Solvolysis
Biochemistry
2-Norbornyl cation
Catalysis

Details

ISSN :

15205126 and 00027863

Volume :

91

Database :

OpenAIRE

Journal :

Journal of the American Chemical Society

Accession number :

edsair.doi...........89bd5accdb063be9087b49b2915c85c2

Full Text :

https://doi.org/10.1021/ja01052a053