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On the Superior Activity of In(I) versus In(III) Cations Toward ortho-C-Alkylation of Anilines and Intramolecular Hydroamination of Alkenes
- Source :
- The Journal of Organic Chemistry. 85:12947-12959
- Publication Year :
- 2020
- Publisher :
- American Chemical Society (ACS), 2020.
-
Abstract
- An efficient ortho-C-alkylation of unprotected anilines with a variety of styrenes and alkenes using a univalent cationic indium(I) catalyst is reported. Mechanistic studies revealed that the react...
- Subjects :
- inorganic chemicals
010405 organic chemistry
organic chemicals
digestive, oral, and skin physiology
Organic Chemistry
Cationic polymerization
chemistry.chemical_element
respiratory system
Alkylation
010402 general chemistry
01 natural sciences
Medicinal chemistry
0104 chemical sciences
Catalysis
chemistry
Intramolecular force
heterocyclic compounds
Hydroamination
Indium
Subjects
Details
- ISSN :
- 15206904 and 00223263
- Volume :
- 85
- Database :
- OpenAIRE
- Journal :
- The Journal of Organic Chemistry
- Accession number :
- edsair.doi...........8a2feecf6a2563664c82666988c82f6e