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Calculation and simulation of the polymerization of isobutylene as a fast reaction

Authors :
Al. Al. Berlin
K. S. Minsker
N.S. Yenikolopyan
Yu. A. Sangalov
Kirillov Aleksandr P
A.G. Svinukhov
V.G. Oshmyan
Source :
Polymer Science U.S.S.R.. 22:625-634
Publication Year :
1980
Publisher :
Elsevier BV, 1980.

Abstract

A mathematical analysis of the kinetics of the rapid polymerization of isobutylene has been made; this has been done with a continuous scheme in which the special features of the properties of the reaction medium and the technological parameters of the reaction behaviour are taken into account. It has been shown that rapid reaction with local introduction of the catalyst occur in separate zones as a “flame” with different temperatures and kinetic parameters: this is accompanied by the formation of a polymer with enhanced molecular non-uniformity. The calculated data have been compared with experimental data and they have been found to agree.

Details

ISSN :
00323950
Volume :
22
Database :
OpenAIRE
Journal :
Polymer Science U.S.S.R.
Accession number :
edsair.doi...........8a57d421c4fec8976607aabd14142069
Full Text :
https://doi.org/10.1016/0032-3950(80)90387-1