Back to Search Start Over

A new hyperbranched water-splitting technique based on Co3O4/MoS2 nano composite catalyst for High-Performance of hydrogen evolution reaction

Authors :
Ali Asghar Sangah
Muhammad Rafique Daudpoto
Yaser A. El-Badry
Nasrullah Mugheri
Zeinhom M. El-Bahy
Abdul Qayoom Mugheri
Source :
International Journal of Hydrogen Energy. 47:2124-2133
Publication Year :
2022
Publisher :
Elsevier BV, 2022.

Abstract

Due to the extensive use of fossil fuels & their direct influence on the environment, new ways of producing energy sources are highly needed. Hydrogen is the perfect candidate for renewable energy; however, H2 gas production is associated with disadvantages due to a lack of efficient and active catalysts that could be cost-effective and comparable to platinum performance. Active hydrogen evolution reaction catalysts are needed to advance the development of a cheaper generation of solar fuels. Thus, outperformance, and stable earth abundant. And inexpensive catalysts are highly demanded. That is H2 gas production from the electrolysis of water through HER. In this work, we present different analytical techniques that characterize an efficient and highly stable catalyst based on transition metal oxide Co3O4/MoS2 nanostructures. And their composites for water splitting in harsh acidic conditions time and material chemical composition as like SEM, EDS, XRD, HRTEM & XPS. The composite material is highly best to produce HER at 10 mA cm−2 and obtained 268 mV overpotential of nano Co3O4/MoS2 (S3) and Tafel slope of 56 mv/dec. Faraday efficiencies of the hydrogen gas production measured for the 60 min and catalyst is highly durable for the 20 h. The presented catalysts are up to the mark of platinum metal performance and superior to several transition metal oxides. This fabrication technology is a new roadmap for developing active and scalable hydrogen-evolving catalysts by overcoming the issues of fewer catalytic edges, low density, and poor conductivity.

Details

ISSN :
03603199
Volume :
47
Database :
OpenAIRE
Journal :
International Journal of Hydrogen Energy
Accession number :
edsair.doi...........8c9bb31c2437cec0ed08746cd7f44c82
Full Text :
https://doi.org/10.1016/j.ijhydene.2021.10.173