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Crystal Structure of a New POM-based Organic-Inorganic Hybrid: {[Cu(2,2'-bipy)Cl]2}n{[Na5(H2O)14](TeMo6O24)}n 2nH2O
- Source :
- Analytical Sciences: X-ray Structure Analysis Online. 23:X235-X236
- Publication Year :
- 2007
- Publisher :
- Japan Society for Analytical Chemistry, 2007.
-
Abstract
- The title POM-based organic-inorganic hybrid compound consists of one Anderson-type polyoxoanion, two [Cu(2,2′-bipy)Cl]+ cations, five Na+ cations and fourteen coordination H2O molecules and two solvent H2O molecules; the polyoxoanion was linked by Na+ to form a 2D layer. A 2D organic layer is also formed through a π-π stacking interaction. Through weak interactions between the adjacent layers, a 3D supramolecular compound is formed.
Details
- ISSN :
- 13482238
- Volume :
- 23
- Database :
- OpenAIRE
- Journal :
- Analytical Sciences: X-ray Structure Analysis Online
- Accession number :
- edsair.doi...........8ca7714e91bcd3a30848b1eb3f52512f