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Solubility Measurement and the Correlation of 1-Naphthaleneacetic Acid in Pure and Methanol + Water Binary Solvents from T = (278.25 to 323.55) K

Authors :
Yu Zhang
Song Wei
Weizhou Wang
Jin-Qiang Liu
Hui-Hui Wang
Source :
Journal of Chemical & Engineering Data. 62:1292-1301
Publication Year :
2017
Publisher :
American Chemical Society (ACS), 2017.

Abstract

The solubilities of 1-naphthaleneacetic acid (NAA) have been measured by the synthetic method in 10 pure organic solvents including methanol, ethanol, 2-propanol, toluene, acetone, acetonitrile, 1,4-dioxane, 1,2-dichloroethane, ethyl acetate, and tetrahydrofuran and binary methanol + water mixtures from (278.25 to 323.55) K under atmospheric pressure. The modified Apelblat equation, λh equation, and Wilson equation were employed to correlate the solubility data. Furthermore, the solubility of NAA in a binary solvent mixture was regressed with a combined nearly ideal binary solvent/Redlich–Kister (CNIBS/R–K) equation and the hybrid equation. According to the calculations based on these equations, the modified Apelblat equation gave the best correlation results with the experimental data in all selected solvents.

Details

ISSN :
15205134 and 00219568
Volume :
62
Database :
OpenAIRE
Journal :
Journal of Chemical & Engineering Data
Accession number :
edsair.doi...........8f7f41fe07de2d76c9f5a143085dc19b
Full Text :
https://doi.org/10.1021/acs.jced.6b00816