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Solubility Measurement and the Correlation of 1-Naphthaleneacetic Acid in Pure and Methanol + Water Binary Solvents from T = (278.25 to 323.55) K
- Source :
- Journal of Chemical & Engineering Data. 62:1292-1301
- Publication Year :
- 2017
- Publisher :
- American Chemical Society (ACS), 2017.
-
Abstract
- The solubilities of 1-naphthaleneacetic acid (NAA) have been measured by the synthetic method in 10 pure organic solvents including methanol, ethanol, 2-propanol, toluene, acetone, acetonitrile, 1,4-dioxane, 1,2-dichloroethane, ethyl acetate, and tetrahydrofuran and binary methanol + water mixtures from (278.25 to 323.55) K under atmospheric pressure. The modified Apelblat equation, λh equation, and Wilson equation were employed to correlate the solubility data. Furthermore, the solubility of NAA in a binary solvent mixture was regressed with a combined nearly ideal binary solvent/Redlich–Kister (CNIBS/R–K) equation and the hybrid equation. According to the calculations based on these equations, the modified Apelblat equation gave the best correlation results with the experimental data in all selected solvents.
- Subjects :
- General Chemical Engineering
Inorganic chemistry
Ethyl acetate
Analytical chemistry
02 engineering and technology
General Chemistry
010402 general chemistry
01 natural sciences
Toluene
0104 chemical sciences
Solvent
chemistry.chemical_compound
020401 chemical engineering
chemistry
Acetone
Methanol
0204 chemical engineering
Solubility
Acetonitrile
Tetrahydrofuran
Subjects
Details
- ISSN :
- 15205134 and 00219568
- Volume :
- 62
- Database :
- OpenAIRE
- Journal :
- Journal of Chemical & Engineering Data
- Accession number :
- edsair.doi...........8f7f41fe07de2d76c9f5a143085dc19b
- Full Text :
- https://doi.org/10.1021/acs.jced.6b00816