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Convenient method for the selective oxidation of sulfide sulfur in alkylmercaptoalkyl esters of thio- and dithioacids of phosphorus

Authors :
G. V. Zhdanova
T. A. Mastryukova
M. I. Kabachnik
A. É. Shipov
Source :
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science. 32:1255-1260
Publication Year :
1983
Publisher :
Springer Science and Business Media LLC, 1983.

Abstract

1. A general method has been developed for the oxidation of sulfide sulfur in S-mercaptoalkyl esters of thio- and dithioacids of phosphorus to the sulfoxides and sulfones. 2. The oxidative activation metabolites of O-ethyl-S-(methoxycarbonylmethylmercaptomethyl) methyldithiophosphonate and its monothio analog, and the hydrolytic detoxification metabolite of the former, have been synthesized.

Details

ISSN :
15739171 and 05685230
Volume :
32
Database :
OpenAIRE
Journal :
Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Accession number :
edsair.doi...........9006da75b42c540cfb0cadf455fa0774
Full Text :
https://doi.org/10.1007/bf00953168