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On the structure and chiroptical properties of (S)-4-isopropyl-oxazolidin-2-one

Authors :
David M. Benoit
Jason Eames
Elliot Coulbeck
Majid Motevalli
Source :
Tetrahedron: Asymmetry. 19:1068-1077
Publication Year :
2008
Publisher :
Elsevier BV, 2008.

Abstract

The specific rotation of (S)-4-isopropyl-oxazolidin-2-one is extremely solvent dependent. In chloroform it is dextrorotatory { [ α ] D 26 = + 15.5 ( c 5.2 , CHCl 3 ) } , whereas in ethanol it is levorotatory { [ α ] D 26 = - 16.1 ( c 5.2 , EtOH ) } .

Details

ISSN :
09574166
Volume :
19
Database :
OpenAIRE
Journal :
Tetrahedron: Asymmetry
Accession number :
edsair.doi...........90a336f87ff8cb7fb45031c1bab68d0f
Full Text :
https://doi.org/10.1016/j.tetasy.2008.03.032