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First-principles investigations of Zn (Cd) doping effects on the electronic structure and magnetic properties of CoFe2O4

Authors :
Y. H. Hou
Zhongwu Liu
L. S. Wen
Dechang Zeng
W. Q. Qiu
X. C. Zhong
Hongyu Yu
Yu-Jun Zhao
Source :
Journal of Applied Physics. 109:07A502
Publication Year :
2011
Publisher :
AIP Publishing, 2011.

Abstract

The electronic structures and magnetic properties of spinel Co1-x Zn (Cd)xFe2O4 (x = 0.0, 0.25, 0.5, 0.75, and 1.0) have been studied systematically by the first-principles calculation. The optimized structures show that with increasing Zn (Cd) content the crystal lattice parameter increases by 1.47% (5.13%) when the Co ions are completely replaced by Zn (Cd) ions. The results also indicate that the magnetic moment of Co/Fe ion increases and the total spin magnetic moment linearly increases with the Zn (Cd) doping from 3.00 μB for x = 0.0 up to 10.00 μB for x = 1.0 per formula unit. The electronic distribution in the Co spin-down subband is highly localized for the crystal field splitting between t2g and eg levels in the Zn (Cd) doped CoFe2O4 compounds and the energy band moves downwards while doped with Zn (Cd). Meanwhile, the bandgap decreases with the increase of Zn (Cd) except where x = 1 and the spinel structure is half-metal at some degree of doping.

Details

ISSN :
10897550 and 00218979
Volume :
109
Database :
OpenAIRE
Journal :
Journal of Applied Physics
Accession number :
edsair.doi...........927dc6fef18b7f2e1c92fd33bc8b58d2
Full Text :
https://doi.org/10.1063/1.3535442