Photolysis of 4,5-diazatetracyclo[6.2.1.13,6.02,7]dodeca-4,9-dienes: a formal homo-Cope rearrangement

Authors :: Kazutoshi Yamada
Shigeo Kohmoto
Makoto Yamamoto
Umesh Joshi
Source :: Journal of the Chemical Society, Chemical Communications. :1578
Publication Year :: 1989
Publisher :: Royal Society of Chemistry (RSC), 1989.
Abstract: The first example of a formal homo-Cope rearrangement in azoalkane chemistry is presented; a double bond in the proximity of a denitrogenation site participates in the rearrangement.

Subjects :: chemistry.chemical_classification
chemistry.chemical_compound
Hydrocarbon
Azo compound
chemistry
Double bond
Photodissociation
Molecular Medicine
Sigmatropic reaction
Photochemistry
Cope rearrangement

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