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Czochralski Crystal Growth, Thermal Conductivity, and Magnetic Properties of PrxLa1−xAlO3, where x = 1, 0.75, 0.55, 0.40, 0

Authors :
Jean-François Fagnard
Michael A. Carpenter
Marek Pękała
D.A. Pawlak
Ryszard Diduszko
S. Turczyński
J. Mucha
K. Orlinski
Philippe Vanderbemden
Source :
Crystal Growth & Design. 11:1091-1097
Publication Year :
2011
Publisher :
American Chemical Society (ACS), 2011.

Abstract

Crystals of PrxLa1−xAlO3 solid solution have been grown by the Czochralski method for the first time, to the best of our knowledge. Crystals with high praseodymium concentration tend to grow spirally. The color of the crystals changes with chemical composition. X-ray diffraction shows an increase of the lattice constants with an increase in lanthanum ion concentration. The thermal conductivity has been investigated in the temperature range from 5 to 300 K. Completely different behavior of thermal conductivity is observed at low temperatures for the investigated crystals, whereas it remains roughly constant at high temperatures. The values of magnetic susceptibility lie within the expected range that could be expected for a paramagnetic material.

Details

ISSN :
15287505 and 15287483
Volume :
11
Database :
OpenAIRE
Journal :
Crystal Growth & Design
Accession number :
edsair.doi...........93c2f58da59b0c9d60495018ba97ce0a
Full Text :
https://doi.org/10.1021/cg101273y