On the Red Rectangle optical emission bands

We have observed the Red Rectangle nebula with the Multi-Object Spectrograph on the WIYN telescope. Moderate-resolution spectra (Δλ=0.4 A) in the region of 5800 A were obtained in 3-arcsec apertures at over 50 positions in the nebula. Accurate and precise wavelength calibrations were obtained against a thorium–argon lamp and the sodium lines in the sky and nebula. The peak position and full width at half-maximum of the 5800-A Red Rectangle band (RRB) were measured to beyond 15 arcsec from the star. The shortest wavelength of the band is found to be 5799.10±0.15 A in the rest frame of the nebula. None of the emission bands has intensity coincident with the wavelength of the diffuse interstellar band (DIB) at 5797.11±0.05 A. The 2-A offset cannot be explained by an instrumental, spectroscopic or photophysical effect. The hypothesis that the same molecule may be the carrier of the RRB and the DIB is contradicted by these observations. As a further test of the hypothesis, absorption has been sought that would be due to a potential DIB carrier in the nebula. Tentative evidence for absorption is found in the RRB spectra taken within 9 arcsec of the star; but any absorption has a peak position essentially coincident in wavelength with the band maximum of the emission band.