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Rapid and selective detection of trace Cu2+ by accumulation- reaction-based Raman spectroscopy
- Source :
- Sensors and Actuators B: Chemical. 283:278-283
- Publication Year :
- 2019
- Publisher :
- Elsevier BV, 2019.
-
Abstract
- Developing detection method for trace copper ions (Cu2+) has attracted great attention since Cu2+ ions would threaten to human health, including cellular toxicity, liver damage, and neuro degenerative diseases. In this work, adding L-cysteine (L-Cys) into inositol hexaphosphate (IP6) modified Ag nanoparticles (designated as L-Cys/IP6@Ag) induces the certain aggregation of nanoparticles, resulting in increasng the surface enhanced Raman scattering (SERS) signal of rhodamine 6 G (R6 G). The presence of Cu2+ ions could be adsorbed by IP6 and the concentrated Cu2+ ions could further selectively oxide Cys molecules under certain pH value, which disperses the IP6@Ag again and decreases the SERS signal of R6 G. The linear range of determination of Cu2+ ions is from 10−5 to 10-1° M as well as a low detection concentration is of 10 pM. Furthermore, the L-Cys/IP6@Ag-R6 G-based SERS sensor has been successfully applied to detect trace Cu2+ in river water.
- Subjects :
- inorganic chemicals
Inorganic chemistry
Nanoparticle
chemistry.chemical_element
02 engineering and technology
010402 general chemistry
01 natural sciences
Ion
Rhodamine
symbols.namesake
chemistry.chemical_compound
Adsorption
Materials Chemistry
Molecule
Electrical and Electronic Engineering
Instrumentation
Chemistry
Metals and Alloys
021001 nanoscience & nanotechnology
Condensed Matter Physics
Copper
0104 chemical sciences
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
symbols
0210 nano-technology
Raman spectroscopy
Raman scattering
Subjects
Details
- ISSN :
- 09254005
- Volume :
- 283
- Database :
- OpenAIRE
- Journal :
- Sensors and Actuators B: Chemical
- Accession number :
- edsair.doi...........9560e3bbb5f24a88d41d42bb3664b9e7