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A reapproach to the generation and reaction mechanism of cyclopropylidenes
- Source :
- Acta Chimica Sinica. 7:240-247
- Publication Year :
- 1989
- Publisher :
- Wiley, 1989.
-
Abstract
- By the comparison of the reaction products of gem-dihalocyclopropanes under various conditions, it is suggested that similar to the reactions with metals, the reactive radical intermediates which make the reaction results complicated are formed in the reactions of gem-dihalocyclopropanes with alkyl lithium. Studies on the competitions between ring opening and intramolecular C—H insertions of cyclopropylidenes generated by the reactions of gem-dihalocyclopropanes with metals and discussions on the reaction mechanism are also given in this paper.
- Subjects :
- chemistry.chemical_classification
Reaction mechanism
endocrine system diseases
Physics::Instrumentation and Detectors
Chemistry
chemistry.chemical_element
General Chemistry
Ring (chemistry)
Photochemistry
Organic reaction
Intramolecular force
Elementary reaction
Lithium
Physics::Chemical Physics
Nuclear Experiment
Alkyl
Subjects
Details
- ISSN :
- 02567660
- Volume :
- 7
- Database :
- OpenAIRE
- Journal :
- Acta Chimica Sinica
- Accession number :
- edsair.doi...........95a74003a328b8826b46f357b443d1db