Precise sensing and selection of molecules by the interface between the metal nanocluster and the oxide support

Molecules being adsorbed on the surface dramatically change the physics and the chemistry of the substrate, thus offering an opportunity for precise sensing of the molecules via monitoring the transformation of the state of the adsorbent. Combination of different types of substrates, forming the surface interface border, generally exhibits synergistic effect dramatically enhancing sensitivity factor. In this regard, the aim of the present work is to demonstrate how the metal/oxide interface, formed in-vacuo (10-10 Torr) by deposition of metal nanoclusters on oxide support, affects behavior of NO and CO molecules being adsorbed on the surface. Coadsorption of NO and CO molecules on the Ni clusters deposited on MgO(111) film formed on Mo(110) crystal has been studied by reflection-absorption infrared spectroscopy (RAIRS) and temperature programmed desorption (TPD). Observed high sensitivity of metal/oxide interface to the molecular behaviour suggests an opportunity for design of new molecular sensors based on the metal/oxide nanostructures.