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Low thermal conductivity in La2Zr2O7 pyrochlore with A-site partially substituted with equimolar Yb2O3 and Er2O3
- Source :
- Ceramics International. 40:9151-9157
- Publication Year :
- 2014
- Publisher :
- Elsevier BV, 2014.
-
Abstract
- (La 1−2 x Yb x Er x ) 2 Zr 2 O 7 ceramics were synthesized using the solid state reaction method and their thermophysical properties were investigated. All (La 1−2 x Yb x Er x ) 2 Zr 2 O 7 ceramics were composed of the pure pyrochlore phase. The average thermal expansion coefficients of the (La 1−2 x Yb x Er x ) 2 Zr 2 O 7 ceramics ranged from 9.54 to 9.78×10 −6 K −1 . The substitution of Yb 3+ and Er 3+ for La 3+ substantially reduced the thermal conductivity of La 2 Zr 2 O 7 . The thermal conductivity decreased from 2.12 W m −1 K −1 for the composition with x =0 to 1.27 W m −1 K −1 for which with x =0.05 at 26 °C. In addition, the thermal conductivity for the composition with x = 0.05 was less sensitive to temperature variation, which ranged from 1.22 to 1.32 W m −1 K −1 in the measuring temperature range. These results suggested promising potential applications of the (La 1−2 x Yb x Er x ) 2 Zr 2 O 7 ceramics for high temperature thermal barrier coatings.
- Subjects :
- Materials science
Process Chemistry and Technology
Analytical chemistry
Pyrochlore
Mineralogy
engineering.material
Temperature measurement
Thermal expansion
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Solid state reaction method
Thermal barrier coating
Thermal conductivity
Phase (matter)
visual_art
Materials Chemistry
Ceramics and Composites
engineering
visual_art.visual_art_medium
Ceramic
Subjects
Details
- ISSN :
- 02728842
- Volume :
- 40
- Database :
- OpenAIRE
- Journal :
- Ceramics International
- Accession number :
- edsair.doi...........9739836f9d42faf633292e955d632862