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The effects of manganese precursors on NO catalytic removal with MnOx/SiO2 catalyst at low temperature
- Source :
- Reaction Kinetics, Mechanisms and Catalysis. 130:195-215
- Publication Year :
- 2020
- Publisher :
- Springer Science and Business Media LLC, 2020.
-
Abstract
- The low-temperature catalytic NO removal efficiencies of catalysts with two different manganese precursors, manganese acetate (αMA catalyst) and manganese nitrate (αMN catalyst), were compared and studied. The NH3-SCR of NO tests using these catalysts were carried out in a self-made reaction device to measure the catalytic activity of the catalysts. Moreover, the reaction pathway analysis of NH3-SCR of NO on the surface of MnO2/SiO2 catalyst and Mn2O3/SiO2 catalyst were performed based on DFT calculations individually. The experimental results show that the NO conversion of αMN catalyst is higher than the αMA catalyst at low temperature (
- Subjects :
- 010405 organic chemistry
Inorganic chemistry
chemistry.chemical_element
Activation energy
Manganese
010402 general chemistry
01 natural sciences
Decomposition
Catalysis
0104 chemical sciences
Crystal
chemistry.chemical_compound
Nitrate
chemistry
X-ray photoelectron spectroscopy
Phase (matter)
Physical and Theoretical Chemistry
Subjects
Details
- ISSN :
- 18785204 and 18785190
- Volume :
- 130
- Database :
- OpenAIRE
- Journal :
- Reaction Kinetics, Mechanisms and Catalysis
- Accession number :
- edsair.doi...........974dd044efe360cea4e84fd21760fd72