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The effects of manganese precursors on NO catalytic removal with MnOx/SiO2 catalyst at low temperature

Authors :
Yuliang Wei
Keting Gui
Dongdong Ren
Shaochen Gu
Source :
Reaction Kinetics, Mechanisms and Catalysis. 130:195-215
Publication Year :
2020
Publisher :
Springer Science and Business Media LLC, 2020.

Abstract

The low-temperature catalytic NO removal efficiencies of catalysts with two different manganese precursors, manganese acetate (αMA catalyst) and manganese nitrate (αMN catalyst), were compared and studied. The NH3-SCR of NO tests using these catalysts were carried out in a self-made reaction device to measure the catalytic activity of the catalysts. Moreover, the reaction pathway analysis of NH3-SCR of NO on the surface of MnO2/SiO2 catalyst and Mn2O3/SiO2 catalyst were performed based on DFT calculations individually. The experimental results show that the NO conversion of αMN catalyst is higher than the αMA catalyst at low temperature (

Details

ISSN :
18785204 and 18785190
Volume :
130
Database :
OpenAIRE
Journal :
Reaction Kinetics, Mechanisms and Catalysis
Accession number :
edsair.doi...........974dd044efe360cea4e84fd21760fd72