Indium-Mediated Coupling Reactions of .DELTA.-Oxygenated Allyl Halide Derivatives with Aldehydes in Aqueous Media

Authors :: Takuo Narasawa
Takeo Taguchi
Chiseko Sakuma
Tsutomu Morikawa
Source :: Chemical and Pharmaceutical Bulletin. 45:1877-1879
Publication Year :: 1997
Publisher :: Pharmaceutical Society of Japan, 1997.
Abstract: Indium-mediated coupling reactions of δ-oxygenated allyl halide derivatives 1 with aldehydes in aqueous media proceeded at the y-position to give diol derivatives 2. Compound 1 is equivalent to an allylic carbanion 4 with a neighboring oxygen functional group generated in aqueous media.

Subjects :: chemistry.chemical_classification
Allylic rearrangement
Aqueous solution
organic chemicals
Diol
food and beverages
Halide
General Chemistry
General Medicine
Aldehyde
Coupling reaction
Benzaldehyde
chemistry.chemical_compound
chemistry
Drug Discovery
Polymer chemistry
Organic chemistry
Carbanion

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