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BNAH-mediated free radical addition to aromatic imines

Authors :
Dong Zhang
Li Yang
Meizhong Jin
Zhong-Li Liu
You-Cheng Liu
Source :
Tetrahedron Letters. 41:7357-7360
Publication Year :
2000
Publisher :
Elsevier BV, 2000.

Abstract

Benzyl radical is added regioselectively to the carbon–nitrogen double bond of aromatic imines by UV irradiation (λ>300 nm) of a ternary mixture of benzyl bromide/aromatic imines/1-benzyl-1,4-dihydronicotinamide (BNAH) in acetonitrile via a BNAH-mediated photoinduced electron transfer mechanism.

Subjects

Subjects :
chemistry.chemical_classification
Double bond
Chemistry
Organic Chemistry
Photochemistry
Biochemistry
Photoinduced electron transfer
chemistry.chemical_compound
Benzyl bromide
Drug Discovery
Irradiation
Ternary operation
Acetonitrile
Free-radical addition

Details

ISSN :
00404039
Volume :
41
Database :
OpenAIRE
Journal :
Tetrahedron Letters
Accession number :
edsair.doi...........9b81bf0fcb89485bbeb4de7b5fbbb5c5

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