ChemInform Abstract: anti-Markovnikov Hydroalkylation of Allylic Amine Derivatives via a Palladium-Catalyzed Reductive Cross-Coupling Reaction

Authors :: Matthew S. Sigman
Ryan J. DeLuca
Source :: ChemInform. 43
Publication Year :: 2011
Publisher :: Wiley, 2011.
Abstract: Palladium-catalyzed hydroalkylation of allylic amines with alkylzinc reagents proceeds with high to excellent chemoselectivity in favor of anti-Markovnikov products in most cases (linear-to-branched ratio from 8:1 up to

Subjects :: Allylic rearrangement
Chemistry
Reagent
Markovnikov's rule
chemistry.chemical_element
General Medicine
Chemoselectivity
Combinatorial chemistry
Coupling reaction
Catalysis
Palladium
Amine derivatives

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