Back to Search
Start Over
Convenient one-pot synthesis of vinylic sulfides from thioalkynes via a catalytic hydroboration-coupling sequence
- Source :
- The Journal of Organic Chemistry. 58:5351-5354
- Publication Year :
- 1993
- Publisher :
- American Chemical Society (ACS), 1993.
-
Abstract
- A variety of vinylic sulfides are stereospecifically synthesized by the catalytic hydroboration of thioacetylenes with catecholborane followed by cross-coupling of the resulting boron derivatives with organic halides. The use of the same palladium catalyst for both stages allows the whole transformation to be carried out in one flask. The synthetic utility of the method is demonstrated by the transformation of vinylic sulfides into diene, indole, and naphtho[b] furan derivatives
Details
- ISSN :
- 15206904 and 00223263
- Volume :
- 58
- Database :
- OpenAIRE
- Journal :
- The Journal of Organic Chemistry
- Accession number :
- edsair.doi...........9ff868ab4622ee2bdacd87bf974a61ef