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Catalytic properties of palygorskite supported Ru and Pd for efficient oxidation of alcohols

Authors :
Zhiwang Yang
Tian-Jing Li
Ying Feng
Xia Zhao
X.L. Xu
Huan-Huan Duan
Qiao-xiang Kang
Liang Xixi
Chen Wenlong
Ziqiang Lei
Source :
Catalysis Communications. 65:34-40
Publication Year :
2015
Publisher :
Elsevier BV, 2015.

Abstract

Natural palygorskite (PG) was employed to prepare cost-effective, reusable supported catalyst of Pd/PG and Ru/PG through wet impregnation method. The catalysts were characterized through AFM, ICP-AES, XPS, XRD, BET, TEM and FTIR. The catalytic properties of the synthesized catalysts were assessed and optimized through oxidation of alcohols with PhIO as oxidant. It showed that the existence of Ru and Pd in the catalysts dramatically enhanced the catalytic activity with a prominent selectivity of far more than 99% compared with the palygorskite.

Details

ISSN :
15667367
Volume :
65
Database :
OpenAIRE
Journal :
Catalysis Communications
Accession number :
edsair.doi...........a0049f337c9aa7629a9bc0978a93e1c7