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Reactions of a Stable Phosphinyl Radical with Stable Aminoxyl Radicals

Authors :
Takeaki Iwamoto
Shintaro Ishida
Fumiya Hirakawa
Source :
Chemistry Letters. 44:94-96
Publication Year :
2015
Publisher :
The Chemical Society of Japan, 2015.

Abstract

Reaction of stable phosphinyl radical 1a with AZADO gave aminoxyphosphine 3 as the primary product by selective radical coupling at −40 °C. Compound 3 decomposed to phosphorane 4, silyl phosphinate...

Details

ISSN :
13480715 and 03667022
Volume :
44
Database :
OpenAIRE
Journal :
Chemistry Letters
Accession number :
edsair.doi...........a196086decd2c7eaef2271aee17a6274
Full Text :
https://doi.org/10.1246/cl.140885