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The structural dependence of the inductive effect. Part II. The shielding of fluorine bonded to octahedral tin(IV) complexes

Authors :
V. Wray
L. Phillips
Source :
Journal of the Chemical Society B: Physical Organic. :2074
Publication Year :
1971
Publisher :
Royal Society of Chemistry (RSC), 1971.

Abstract

A procedure used to calculate chemical shifts in some fluorocarbon compounds (see preceding paper) is extended to include fluorine bonded to tin(IV). In this case secondary interactions, responsible for deviations from additivity of substituent effects in fluorocarbons, are negligible.

Details

ISSN :
00456470
Database :
OpenAIRE
Journal :
Journal of the Chemical Society B: Physical Organic
Accession number :
edsair.doi...........a5225409702187c29fb4e17603975109