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NickelII-catalyzed asymmetric photoenolization/Mannich reaction of (2-alkylphenyl) ketones

Authors :
Liangkun Yang
Wang-Yuren Li
Liuzhen Hou
Tangyu Zhan
Weidi Cao
Xiaohua Liu
Xiaoming Feng
Source :
Chemical Science. 13:8576-8582
Publication Year :
2022
Publisher :
Royal Society of Chemistry (RSC), 2022.

Abstract

A diastereo- and enantioselective photoenolization/Mannich (PEM) reaction of (2-alkylphenyl) ketones with benzosulfonimides is realized by a chiral N,N′-dioxide/NiII complex catalyst.

Subjects

Subjects :
General Chemistry

Details

ISSN :
20416539 and 20416520
Volume :
13
Database :
OpenAIRE
Journal :
Chemical Science
Accession number :
edsair.doi...........a5943b251939dbf98aa965f13c17e7d9