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The reaction of HV(CO)4dppe with MoO3: a well-defined model of hydrogen spillover
- Source :
- Catalysis Science & Technology. 11:7540-7544
- Publication Year :
- 2021
- Publisher :
- Royal Society of Chemistry (RSC), 2021.
-
Abstract
- Hydrogen spillover is mechanistically poorly understood, due to the H˙ donor complexity. We show that HV(CO)4dppe (1) transfers H˙ to MoO3 in separate H+ and e− transfer steps. This is analogous to hydrogen spillover from Pt to MoO3 and suggests that 1 is a good model for H˙ adsorbed on Pt.
- Subjects :
- Adsorption
Chemistry
Hydrogen spillover
Photochemistry
Catalysis
Subjects
Details
- ISSN :
- 20444761 and 20444753
- Volume :
- 11
- Database :
- OpenAIRE
- Journal :
- Catalysis Science & Technology
- Accession number :
- edsair.doi...........a621b204c7d909d26107f693232dc66e
- Full Text :
- https://doi.org/10.1039/d1cy01374b