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Tartaric acid catalyzed furfurylation of beech wood
- Source :
- Wood Science and Technology. 51:379-394
- Publication Year :
- 2016
- Publisher :
- Springer Science and Business Media LLC, 2016.
-
Abstract
- European beech (Fagus sylvatica L.) is a major tree species of European forest which is underexploited because of its low dimensional stability and durability. Similarly to what has been developed with radiata pine, furfurylation might be the answer to optimize the utilization of local beech wood. Beech wood furfurylation process was studied using five different catalysts: maleic anhydride, maleic acid, citric acid, itaconic acid, and tartaric acid. Optimization of the furfurylation process was investigated for different catalyst and furfuryl alcohol (FA) contents, and different duration of polymerization. The following properties were studied: weight percent gain (WPG), leachability, anti-swelling efficiency (ASE), wettability, modulus of elasticity, modulus of rupture, Brinell hardness, and decay durability. Tartaric acid, never investigated up to now, was retained as catalyst to perform furfurylation due to its efficacy compared to other catalysts and its novelty. Wood modification with FA and tartaric acid as catalyst led to samples with high WPG even after leaching, improved ASE, and lower wettability with water. Increasing the polymerization duration increased the fixation of FA in treated wood. Most of all, treatment gave a significant improvement in mechanical properties and resistance to wood decaying fungi.
- Subjects :
- 040101 forestry
0106 biological sciences
Materials science
biology
Maleic acid
Maleic anhydride
Forestry
04 agricultural and veterinary sciences
Plant Science
biology.organism_classification
01 natural sciences
Industrial and Manufacturing Engineering
Furfuryl alcohol
chemistry.chemical_compound
chemistry
Fagus sylvatica
010608 biotechnology
Tartaric acid
0401 agriculture, forestry, and fisheries
Organic chemistry
General Materials Science
Itaconic acid
Citric acid
Beech
Subjects
Details
- ISSN :
- 14325225 and 00437719
- Volume :
- 51
- Database :
- OpenAIRE
- Journal :
- Wood Science and Technology
- Accession number :
- edsair.doi...........a6fccd9323e8c85d2272a3928653431e
- Full Text :
- https://doi.org/10.1007/s00226-016-0871-8