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Tartaric acid catalyzed furfurylation of beech wood

Authors :
Stéphane Dumarçay
Prabu Satria Sejati
Trisna Priadi
Phillipe Gérardin
Christine Gérardin-Charbonnier
Aurélia Imbert
Eric Masson
Emmanuel Fredon
Dodi Nandika
Source :
Wood Science and Technology. 51:379-394
Publication Year :
2016
Publisher :
Springer Science and Business Media LLC, 2016.

Abstract

European beech (Fagus sylvatica L.) is a major tree species of European forest which is underexploited because of its low dimensional stability and durability. Similarly to what has been developed with radiata pine, furfurylation might be the answer to optimize the utilization of local beech wood. Beech wood furfurylation process was studied using five different catalysts: maleic anhydride, maleic acid, citric acid, itaconic acid, and tartaric acid. Optimization of the furfurylation process was investigated for different catalyst and furfuryl alcohol (FA) contents, and different duration of polymerization. The following properties were studied: weight percent gain (WPG), leachability, anti-swelling efficiency (ASE), wettability, modulus of elasticity, modulus of rupture, Brinell hardness, and decay durability. Tartaric acid, never investigated up to now, was retained as catalyst to perform furfurylation due to its efficacy compared to other catalysts and its novelty. Wood modification with FA and tartaric acid as catalyst led to samples with high WPG even after leaching, improved ASE, and lower wettability with water. Increasing the polymerization duration increased the fixation of FA in treated wood. Most of all, treatment gave a significant improvement in mechanical properties and resistance to wood decaying fungi.

Details

ISSN :
14325225 and 00437719
Volume :
51
Database :
OpenAIRE
Journal :
Wood Science and Technology
Accession number :
edsair.doi...........a6fccd9323e8c85d2272a3928653431e
Full Text :
https://doi.org/10.1007/s00226-016-0871-8