Back to Search
Start Over
A Full Li–S Battery with Ultralow Excessive Li Enabled via Lithiophilic and Sulfilic W 2 C Modulation
- Source :
- Chemistry – A European Journal. 26:16057-16065
- Publication Year :
- 2020
- Publisher :
- Wiley, 2020.
-
Abstract
- The practical application of Li-S batteries demands low cell balance (Licapacity /Scapacity ), which involves uniform Li growth, restrained shuttle effect, and fast redox reaction kinetics of S species simultaneously. Herein, with the aid of W2 C nanocrystals, a freestanding 3D current collector is applied as both Li and S hosts owing to its lithiophilic and sulfilic property. On the one hand, the highly conductive W2 C can reduce Li nucleation overpotentials, thus guiding uniform Li nucleation and deposition to suppress Li dendrite growth. On the other hand, the polar W2 C with catalytic effect can enhance the chemisorption affinity to lithium polysulfides (LiPSs) and guarantee fast redox kinetics to restrain S species in cathode region and promote the utilization of S. Surprisingly, a full Li-S battery with ultralow cell balance of 1.5:1 and high sulfur loading of 6.06 mg cm-2 shows obvious redox plateaus of S and maintains high reversible specific capacity of 1020 mAh g-1 (6.2 mAh cm-2 ) after 200 cycles. This work may shed new sights on the facile design of full Li-S battery with low excessive Li supply.
- Subjects :
- Battery (electricity)
010405 organic chemistry
Organic Chemistry
Nucleation
chemistry.chemical_element
General Chemistry
Current collector
010402 general chemistry
01 natural sciences
Redox
Catalysis
Cathode
0104 chemical sciences
law.invention
chemistry
Nanocrystal
Chemical engineering
Chemisorption
law
Lithium
Subjects
Details
- ISSN :
- 15213765 and 09476539
- Volume :
- 26
- Database :
- OpenAIRE
- Journal :
- Chemistry – A European Journal
- Accession number :
- edsair.doi...........a79c5d7847e56c66a6e0aa89578c4946