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Vacuum ultraviolet photolysis of CClF2CH2Cl

Authors :
Masayuki Iwasaki
Yukio H. Ogata
S. Ogura
Tetsuo Sakka
Tadahiro Minamikawa
Source :
International Journal of Chemical Kinetics. 26:561-569
Publication Year :
1994
Publisher :
Wiley, 1994.

Abstract

Photolysis of CClF2CH2Cl was studied by 147 nm vacuum ultraviolet irradiation. In the presence of NO; CF2CH2, CF2CHCl, and CClF2CN were produced. These products represent three different reaction paths; the molecular dechlorination, molecular dehydrochlorination, and chlorine radical elimination reactions. The reactant pressure and the addition gas (He or NO) pressure effects upon the product yield were studied. © 1994 John Wiley & Sons, Inc.

Details

ISSN :
10974601 and 05388066
Volume :
26
Database :
OpenAIRE
Journal :
International Journal of Chemical Kinetics
Accession number :
edsair.doi...........aaf62bfff075d83299b644e0b84d7418
Full Text :
https://doi.org/10.1002/kin.550260509