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An unusual autocatalysis with an air-stable Pd complex to promote enantioselective synthesis of Si-stereogenic enynes
- Source :
- Chemical Science. 14:1123-1131
- Publication Year :
- 2023
- Publisher :
- Royal Society of Chemistry (RSC), 2023.
-
Abstract
- A highly enantioselective palladium-catalyzed hydrosilylation of 1,3-diynes with dihydrosilanes was established for the facile preparation of Si-stereogenic enynes and an enyne-linked chiral polymer (polyenyne) in good yields with excellent ees.
- Subjects :
- General Chemistry
Subjects
Details
- ISSN :
- 20416539 and 20416520
- Volume :
- 14
- Database :
- OpenAIRE
- Journal :
- Chemical Science
- Accession number :
- edsair.doi...........aaf6b2d49339d44788ee4171be97f224