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Phase equilibria in the systems 3-methylpentane + methylcyclohexane, diisopropyl ether + methylcyclohexane and 3-methylpentane + diisopropyl ether + methylcyclohexane at 101.3 kPa

Authors :
Antonio Aucejo
Sonia Loras
Rosa Muñoz
Source :
Fluid Phase Equilibria. :957-968
Publication Year :
2002
Publisher :
Elsevier BV, 2002.

Abstract

Consistent vapor–liquid equilibria (VLE) at 101.3 kPa has been determined for the ternary system 3-methylpentane+diisopropyl ether (DIPE)+methylcyclohexane and the binary subsystems 3-methylpentane+methylcyclohexane and DIPE+methylcyclohexane in the temperature range from 336 to 374 K. According to the experimental results, the systems exhibit slight positive deviation from ideal behavior and no azeotrope is present. The VLE data have been correlated with the composition using the Wilson, UNIQUAC and NRTL relations. These models allow good prediction of the VLE properties of the ternary system from those of the pertinent binary subsystems.

Details

ISSN :
03783812
Database :
OpenAIRE
Journal :
Fluid Phase Equilibria
Accession number :
edsair.doi...........ad2c614730aaaa203432f67d2aa48ee9
Full Text :
https://doi.org/10.1016/s0378-3812(01)00653-7