Chemistry of Silyl Thioketones. Part 6. Synthesis of 5-Membered Silyl-heterocycles via 1,3-Dipolar Cycloaddition to Aryl Silyl Thioketones

Authors :: Ghamel Abdel-Lateef
Achmed Atwa
G. Mazzanti
Gaetano Barbaro
G. Maccagnani
P. Zani
B. F. Bonini
Source :: HETEROCYCLES. 31:47
Publication Year :: 1990
Publisher :: The Japan Institute of Heterocyclic Chemistry, 1990.
Abstract: Aryl silyl thioketones react with 1,3-dipoles (nitriloxides, nitrilimine and nitrile ylide) to give regiospecifically silyl thiaheterocycles. These cycloadducts undergo desilylation leading either to ring fragmentation products or to the H-substituted heterocycles

Subjects :: Pharmacology
chemistry.chemical_classification
Silylation
Nitrilimine
Aryl
Organic Chemistry
Ring (chemistry)
Medicinal chemistry
Analytical Chemistry
chemistry.chemical_compound
chemistry
Fragmentation (mass spectrometry)
1,3-Dipolar cycloaddition
Organic chemistry
Nitrile ylide

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