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ChemInform Abstract: Alkenyl-Substituted Ketals as Efficient Precursors to Claisen Rearrangement Substrates

Authors :
Hemaka A. Rajapakse
Rebecca C. Hoye
Source :
ChemInform. 28
Publication Year :
2010
Publisher :
Wiley, 2010.

Abstract

Alkenyl-substituted ketals 6 readily afford Claisen rearrangement substrates 7 upon treatment with TESOTf/DIPEA. Thermal rearrangement completes this efficient and general process for generation of functionally rich ϵ-oxy-γ,δ-enones 8.

Details

ISSN :
09317597
Volume :
28
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........ae77fcdff698647b34643ea43d5d6a39
Full Text :
https://doi.org/10.1002/chin.199726062