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Disinfection of urine by conductive-diamond electrochemical oxidation
- Source :
- Applied Catalysis B: Environmental. 229:63-70
- Publication Year :
- 2018
- Publisher :
- Elsevier BV, 2018.
-
Abstract
- This work focuses on the application of electrolysis with diamond anodes for the disinfection of urine. To do this, a synthetic human urine was polluted with Escherichia coli and Pseudomonas aeruginosa and then, it was electrolyzed at current densities within the range 0–100 A m−2. Results show that it is possible to disinfect completely the effluent even at applied electric charges lower than 2 kAh m−3, regardless the current density applied. This good performance is related to the production of powerful oxidants from the oxidation of the ions present in synthetic urine. Likewise, these species also react with the organics contained in urine (urea, creatinine and uric acid), favoring their degradation. The process efficiency for both microorganisms and organics is higher when working at low current densities. The removal of organics leads to the release of significant amounts of nitrogen in the form of nitrate which are later electroreduced to ammonium, that, in turn, reacts with the electrogenerated hypochlorite, favoring the production of chloramines (which can also contribute to the disinfection process). Regarding the mineralization, TOC removal higher than 90% can be achieved but higher applied electric charges than those required for disinfection have to be applied (around 30 kAh m−3).
- Subjects :
- Chloramine
Electrolysis
Process Chemistry and Technology
Inorganic chemistry
chemistry.chemical_element
Hypochlorite
02 engineering and technology
Mineralization (soil science)
010501 environmental sciences
021001 nanoscience & nanotechnology
01 natural sciences
Nitrogen
Catalysis
law.invention
chemistry.chemical_compound
chemistry
law
Urea
Ammonium
0210 nano-technology
Effluent
0105 earth and related environmental sciences
General Environmental Science
Subjects
Details
- ISSN :
- 09263373
- Volume :
- 229
- Database :
- OpenAIRE
- Journal :
- Applied Catalysis B: Environmental
- Accession number :
- edsair.doi...........b147ea67867c522a7bf4a92846adc7b5