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Determining the limiting factor of the electrochemical stability window for PEO-based solid polymer electrolytes: main chain or terminal –OH group?
- Source :
- Energy & Environmental Science. 13:1318-1325
- Publication Year :
- 2020
- Publisher :
- Royal Society of Chemistry (RSC), 2020.
-
Abstract
- Due to higher energy density, high-voltage all-solid-state lithium batteries (ASSLBs) have attracted increasing attention. However, they require solid-state electrolytes (SSEs) with wide electrochemical stability windows (ESW, typically >4.2 V) and high-stability against the Li anode. Nevertheless, poly(ethylene oxide) (PEO), the most widely used solid polymer electrolyte (SPE), can’t tolerate a high-voltage over 4 V. Whether the main chain (–C–O–C–) or the terminal hydroxide group (–OH) is the limiting factor for the narrow ESW remains unknown. Herein, poly(ethylene glycol) (PEG) and poly(ethylene glycol)dimethyl ether (PEGDME) with different terminal groups are selected to answer this question. The results show that the reactive terminal –OH group is the limiting factor towards applicability against high voltage and the Li anode. Replacing –OH with more stable –OCH3 can significantly extend the ESW from 4.05 to 4.3 V, while improving the Li-anode compatibility as well (Li–Li symmetric cells stably run for 2500 h at 0.2 mA cm−2). Its practical application is further proved by developing PEGDME-based ASSLB pouch cells. The 0.53 mA cm−2 Li–LiFePO4 and 0.47 mA h cm−2 Li–LiNi0.5Mn0.3Co0.2O2 cells demonstrated high capacity retention of 97% and 90% after 210 cycles and 110 cycles, respectively. This work offers a new strategy for PEO-based high-voltage ASSLB development by changing the unstable terminal groups.
- Subjects :
- chemistry.chemical_classification
Materials science
Ethylene oxide
Renewable Energy, Sustainability and the Environment
02 engineering and technology
Polymer
Electrolyte
010402 general chemistry
021001 nanoscience & nanotechnology
Electrochemistry
01 natural sciences
Pollution
0104 chemical sciences
Anode
chemistry.chemical_compound
Nuclear Energy and Engineering
chemistry
Chemical engineering
Environmental Chemistry
Hydroxide
Dimethyl ether
0210 nano-technology
Ethylene glycol
Subjects
Details
- ISSN :
- 17545706 and 17545692
- Volume :
- 13
- Database :
- OpenAIRE
- Journal :
- Energy & Environmental Science
- Accession number :
- edsair.doi...........b33863ef68f7a4abc990d6992accde2b