Magnetocaloric effect of monovalent K doped manganites Pr0.6Sr0.4−xKxMnO3 (x=0 to 0.2)

Magnetic and magnetocaloric properties are reported for polycrystalline monovalent potassium doped manganites Pr0.6Sr0.4−xKxMnO3 (x=0, 0.05, 0.1, 0.15 and 0.2) crystallized in orthorhombic structure with Pnma space group. The increasing K content shifts the paramagnetic to ferromagnetic transition temperature from 310 K for x=0 to 269 K for x=0.2. The magnetic entropy change under magnetic field variation of 2 T is found to be 1.95, 3.09, 2.89, 3.05 and 3.2 J/kgK for x varying from 0 to 0.2, respectively. The highest relative cooling power of 102 J/kg is observed for the undoped sample. The sensitivity of magnetic entropy change to magnetic field is estimated by a local N(T) exponent exhibiting the characteristic temperature variation. Phenomenological universal curves of entropy change and Arrott plots confirm the second order phase transition.