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Expanded Scope of the Asymmetric Hydrogenation of Minimally Functionalized Olefins Catalyzed by Iridium Complexes with Phosphite-Thiazoline Ligands
- Source :
- ChemCatChem. 5:2410-2417
- Publication Year :
- 2013
- Publisher :
- Wiley, 2013.
-
Abstract
- We have replaced the oxazoline group with a thiazoline moiety in one of the most successful of the phosphite–oxazoline ligand families for the Ir-catalyzed hydrogenation of minimally functionalized olefins. A small but structurally important library of Ir phosphite–thiazoline precatalysts (Ir-L1–L2 a–e) has been developed by changing the substituents/configurations at the biaryl phosphite group. We found that the replacement of the oxazoline with a thiazoline moiety in the ligand design is beneficial in terms of substrate scope.
Details
- ISSN :
- 18673880
- Volume :
- 5
- Database :
- OpenAIRE
- Journal :
- ChemCatChem
- Accession number :
- edsair.doi...........b417bdf99ac2c27bb0336a6a0cae4ace