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Analyzing Structural and Physicochemical Characteristics of Bismuth-Promoted Fe-Containing Catalysts of CO Hydrogenation
- Source :
- Russian Journal of Physical Chemistry A. 94:1996-2003
- Publication Year :
- 2020
- Publisher :
- Pleiades Publishing Ltd, 2020.
-
Abstract
- Carbon material (СAm), prepared on the basis of shadbush (Amelanchier) wood is used as a support of bismuth-promoted (0.6 wt %) Fe-containing catalyst of CO hydrogenation. Structural, morphological, and physicochemical characteristics of the systems are studied. It is established via IR spectroscopy that sub-carbonyl and bridge forms of absorption are observed when bismuth is present on a surface of Fe/СAm during calcination in a stream of CO. At the same time, only iron oxide particles form, substantially facilitating the process of catalyst reduction afterward.
- Subjects :
- Materials science
Iron oxide
chemistry.chemical_element
Infrared spectroscopy
02 engineering and technology
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
0104 chemical sciences
Catalysis
Bismuth
law.invention
chemistry.chemical_compound
chemistry
Chemical engineering
law
Calcination
Physical and Theoretical Chemistry
Absorption (chemistry)
0210 nano-technology
Carbon
Subjects
Details
- ISSN :
- 1531863X and 00360244
- Volume :
- 94
- Database :
- OpenAIRE
- Journal :
- Russian Journal of Physical Chemistry A
- Accession number :
- edsair.doi...........b5246740da63447c0f0a898b877923fc
- Full Text :
- https://doi.org/10.1134/s0036024420100234