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Analyzing Structural and Physicochemical Characteristics of Bismuth-Promoted Fe-Containing Catalysts of CO Hydrogenation

Authors :
A. V. Shumyantsev
Galina V. Pankina
A. N. Kharlanov
Valery V. Lunin
Source :
Russian Journal of Physical Chemistry A. 94:1996-2003
Publication Year :
2020
Publisher :
Pleiades Publishing Ltd, 2020.

Abstract

Carbon material (СAm), prepared on the basis of shadbush (Amelanchier) wood is used as a support of bismuth-promoted (0.6 wt %) Fe-containing catalyst of CO hydrogenation. Structural, morphological, and physicochemical characteristics of the systems are studied. It is established via IR spectroscopy that sub-carbonyl and bridge forms of absorption are observed when bismuth is present on a surface of Fe/СAm during calcination in a stream of CO. At the same time, only iron oxide particles form, substantially facilitating the process of catalyst reduction afterward.

Details

ISSN :
1531863X and 00360244
Volume :
94
Database :
OpenAIRE
Journal :
Russian Journal of Physical Chemistry A
Accession number :
edsair.doi...........b5246740da63447c0f0a898b877923fc
Full Text :
https://doi.org/10.1134/s0036024420100234