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ChemInform Abstract: Intramolecular Heck-Type Reactions in Aqueous Medium. Dramatic Change in Regioselectivity

Authors :
Monique Savignac
Christophe Dupuis
Sandrine Lemaire-Audoire
Jean-Pierre GenĂȘt
Source :
ChemInform. 27
Publication Year :
2010
Publisher :
Wiley, 2010.

Abstract

Efficient intramolecular Heck-type cyclizations were carried out in aqueous medium using water-soluble Pd/TPPTS catalysts. Under these conditions, the generally observed exo process was reversed in favor of the regioselective formation of endo cyclized compounds.

Details

ISSN :
09317597
Volume :
27
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........b561ec9a2bd94e542c612c501495338c
Full Text :
https://doi.org/10.1002/chin.199627050