ChemInform Abstract: Electron-Transfer Catalysis of Olefin Epoxidation with Nitrogen Dioxide (Dinitrogen Tetroxide)

Authors :: Jay K. Kochi
Eric Bosch
Source :: ChemInform. 24
Publication Year :: 2010
Publisher :: Wiley, 2010.
Abstract: The novel epoxidation of diadamantylidene 1 and related hindered olefins with NO2 proceeds by way of the cation radical 1+˙ generated during the electron-transfer chain (ETC) catalysis initiated by nitrosonium.

Subjects :: chemistry.chemical_compound
Electron transfer
Olefin fiber
Ozonolysis
chemistry
Dinitrogen tetroxide
Nitrosonium
Nitrogen dioxide
Dehydrogenation
General Medicine
Photochemistry
Catalysis

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