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Li+ intercalcation pseudocapacitance in Sn-based metal-organic framework for high capacity and ultra-stable Li ion storage
- Source :
- Journal of Power Sources. 440:227162
- Publication Year :
- 2019
- Publisher :
- Elsevier BV, 2019.
-
Abstract
- Tin (Sn)-based materials are potential alternatives to the commercial graphite anode for next-generation Li-ion batteries (LIBs) due to their high theoretical capacity. However, the poor cyclic stability, originating from the large volumetric changes during charge/discharge process, hinder their practical utilization. Herein, we have successfully prepared a Sn-based metal-organic framework (MOF, Sn-PMA), and explored as potential anode materials in LIBs. Benefiting from its layered structure and efficient electron transport channels, Sn-PMA electrodes deliver a high initial capacity of 1567 mAh g−1, at 100 mA g−1, and maintained a reversible capacity of 707 mAh g−1, at 800 mA g−1, after 400 cycles. Furthermore, the detailed post-electrochemical structural, morphological and compositional analysis is carried out to unveil the structural changes and Li-ion storage mechanism of electrodes. Ex-situ XRD and XPS results revealed that, in Sn-PMA electrode, O atom, coordinated to the Sn atom, exhibited higher electronegativity, served as major Li-ion storage site and rendered excellent cyclic stability due to a stable structure. Kinetic analyses reveal that the excellent performance of the Sn-PMA is typical attributed to the pseudocapacitive contribution induced by the special porous structure.
- Subjects :
- Materials science
Renewable Energy, Sustainability and the Environment
Energy Engineering and Power Technology
chemistry.chemical_element
02 engineering and technology
010402 general chemistry
021001 nanoscience & nanotechnology
01 natural sciences
Lithium-ion battery
Pseudocapacitance
0104 chemical sciences
Anode
Electronegativity
Chemical engineering
X-ray photoelectron spectroscopy
chemistry
Electrode
Metal-organic framework
Electrical and Electronic Engineering
Physical and Theoretical Chemistry
0210 nano-technology
Tin
Subjects
Details
- ISSN :
- 03787753
- Volume :
- 440
- Database :
- OpenAIRE
- Journal :
- Journal of Power Sources
- Accession number :
- edsair.doi...........b78bf8f63e2b75bb70e10adb2c9f2e09