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Efficient generation of hydrogen peroxide by aerobic photooxidation of 2-propanol using anthraquinone-2-carboxylic acid and one-pot epoxidation of α,β-unsaturated ketones

Authors :
Akichika Itoh
Lei Cui
Tsuyoshi Miura
Norihiro Tada
Yuma Tachikawa
Sohei Furuhashi
Source :
Tetrahedron Letters. 54:162-165
Publication Year :
2013
Publisher :
Elsevier BV, 2013.

Abstract

We developed an efficient method for the generation of hydrogen peroxide by aerobic photooxidation of 2-propanol using anthraquinone-2-carboxylic acid and molecular oxygen in air and visible light from fluorescent lamps. One-pot epoxidation of α,β-unsaturated ketones using the generated hydrogen peroxide is also reported.

Details

ISSN :
00404039
Volume :
54
Database :
OpenAIRE
Journal :
Tetrahedron Letters
Accession number :
edsair.doi...........b8dd068c911447f87c3befa862e10a12
Full Text :
https://doi.org/10.1016/j.tetlet.2012.10.119