Back to Search Start Over

In situ synthesis of 2-allyloxy-1-methylpyridinium triflate for the allylation of carboxylic acids

Authors :
Philip A. Albiniak
Timothy A. Strayer
Matthew H. Bunner
Amie R. Frank
Caleb C. Culy
Source :
Tetrahedron Letters. 56:6807-6809
Publication Year :
2015
Publisher :
Elsevier BV, 2015.

Abstract

2-Allyloxypyridinium triflate is formed in situ by treating a mixture of 2-allyloxypyridine, a carboxylic acid, and toluene with methyl triflate. Subsequent warming of the reaction mixture in the presence of potassium carbonate leads to efficient formation of allyl esters in good to excellent yields.

Details

ISSN :
00404039
Volume :
56
Database :
OpenAIRE
Journal :
Tetrahedron Letters
Accession number :
edsair.doi...........b95980188b5332ad9ec4e6c13034917a
Full Text :
https://doi.org/10.1016/j.tetlet.2015.10.085