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ChemInform Abstract: Highly Diastereoselective Synthesis of Chiral Furans with a Quaternary Carbon Substituent at the 2-Position Using 8-Phenylmenthol as the Chiral Auxiliary

Authors :
Yohsuke Yamamoto
Akihisa Iwamoto
Satoshi Kojima
Aki Katori
Yoshiaki Sashihara
Source :
ChemInform. 45
Publication Year :
2014
Publisher :
Wiley, 2014.

Abstract

The reaction of cyclopentane and cyclohexane carboxylates with cis-pentenals (II) proceeds in the presence of a fluorinated cosolvent to afford the corresponding furan products with high diastereoselectivity.

Details

ISSN :
09317597
Volume :
45
Database :
OpenAIRE
Journal :
ChemInform
Accession number :
edsair.doi...........b9cef21b369ddea1b5e1813b23f7eadb
Full Text :
https://doi.org/10.1002/chin.201442107