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Rhodium-catalyzed migrative annulation and olefination of 2-aroylpyrroles with diazoesters

Authors :
Daniil M. Strashkov
Kirill V. Zavyalov
Pavel A. Sakharov
Anastasiya V. Agafonova
Nikolai V. Rostovskii
Alexander F. Khlebnikov
Mikhail S. Novikov
Source :
Organic Chemistry Frontiers. 10:506-513
Publication Year :
2023
Publisher :
Royal Society of Chemistry (RSC), 2023.

Abstract

An unprecedented Rh2(OAc)4-catalyzed domino reaction of diazoesters with 2-aroylpyrroles involves four catalytic cycles and can be applied for the synthesis of pyrrolo[1,2-c][1,3]oxazin-1-ones and 2-(pyrrol-2-yl)cinnamate esters.

Subjects

Subjects :
Organic Chemistry

Details

ISSN :
20524129
Volume :
10
Database :
OpenAIRE
Journal :
Organic Chemistry Frontiers
Accession number :
edsair.doi...........baa4b434e6c69817a19cd5f301e2da95
Full Text :
https://doi.org/10.1039/d2qo01759h