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Variational bounds for imaginary frequency polarizability and dispersion interaction constant

Authors :
P. A. Braun
T. K. Rebane
Source :
International Journal of Quantum Chemistry. 6:639-646
Publication Year :
1972
Publisher :
Wiley, 1972.

Abstract

A study is made of a variational principle which provides upper and lower bounds for the polarizability under a perturbation with imaginary frequency. As an example bounds for the imaginary frequency polarizability of atomic hydrogen and ensuing limits for the constant of van-der-Waals interaction of two hydrogen atoms are calculated.

Details

ISSN :
1097461X and 00207608
Volume :
6
Database :
OpenAIRE
Journal :
International Journal of Quantum Chemistry
Accession number :
edsair.doi...........bc3b0f7ea9cde7e30920c2a642f63969