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Synthesis and X-ray Structure of a Platinum η2-Disilene Complex
- Source :
- Organometallics. 21:454-456
- Publication Year :
- 2002
- Publisher :
- American Chemical Society (ACS), 2002.
-
Abstract
- The platinum silyl-substituted η2-disilene complex (Me3P)2Pt[Si(SiMe2(t-Bu))2]2 (4) was synthesized by the reaction of cis-(Me3P)2PtCl2 (5) with 1,2-dilithiotetrakis(tert-butyldimethylsilyl)disilane (6) in THF at −50 °C for 3 h. The X-ray structural analysis revealed that 4 can be regarded as a metalladisilacyclopropane with very weak π-complex character.
Details
- ISSN :
- 15206041 and 02767333
- Volume :
- 21
- Database :
- OpenAIRE
- Journal :
- Organometallics
- Accession number :
- edsair.doi...........bd8c72901dbd2ccefe6d753f5e3f4c89
- Full Text :
- https://doi.org/10.1021/om010914+